ProChemPolygon-product

Vanadium (V) Triisopropoxide Oxide

Properties

Product #
3777
Name
Vanadium (V) Triisopropoxide Oxide
Synonyms
Vanadyl (V) Isopropoxide, Vanadyl Isopropylate, Tri-iso-propylvanadate, Isopropylorthovanadate, VTIP
Formula
VO(OC3H7)3
Purity
99.99%
CAS Number
5588-84-1
Molecular Weight
244.20
Color & Form
Colorless liquid
Boiling Point
176-180° C
Melting Point
45° C
Specific Gravity
1.035
Solubility in water
Decomposes
$185.00
$545.00
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Information about Vanadium (V) Triisopropoxide Oxide / CAS 5588-84-1

Vanadium (V) Triisopropoxide Oxide, also known as Vanadium Oxytriisopropoxide, is a versatile organovanadium compound widely used as a precursor in the synthesis of Vanadium Oxide materials. Its high reactivity, volatility, and controlled decomposition are important characteristics that make it a useful reagent for thin-film deposition, catalysis, and advanced material synthesis. The compound plays a crucial role in laboratory and research applications requiring high-purity Vanadium Oxide films, nanoparticles, and functional coatings, making it valuable for industries such as electronics, energy storage, catalysis, and photovoltaics.

A primary application of Vanadyl (V) Isopropoxide is in chemical vapor deposition (CVD) and atomic layer deposition (ALD), where it serves as a vanadium oxide precursor. Researchers have successfully used Vanadium (V) Triisopropoxide Oxide to fabricate Vanadium Oxide thin films with controlled morphologies and phase compositions, a critical factor in developing next-generation electronic components and optoelectronic devices. These films exhibit tunable electrical and optical properties, making them ideal for sensors, transistors, and transparent conductive coatings. Additionally, Vanadium Oxide-based films are essential for bolometric detectors, infrared sensors, and thermochromic applications, where phase transitions influence their conductivity and optical behavior.

Vanadium Oxytriisopropoxide is a key precursor for Vanadium-based catalysts in oxidation reactions, including hydrocarbon oxidation (e.g., methanol to formaldehyde), biomass conversion into biofuels, and petrochemical refining processes such as oxidative desulfurization. It also plays a crucial role in sulfuric acid production via the Contact Process, where Vanadium Pentoxide enables SO₂ oxidation. Its high solubility and controlled hydrolysis allow for precise incorporation into catalytic systems, leading to enhanced reaction efficiency and selectivity. The compound is extensively used in the production of Vanadium-containing zeolites and mesoporous materials, which are crucial in industrial-scale catalytic processes.

Energy storage researchers benefit significantly from Vanadium-based materials derived from Vanadyl (V) Isopropoxide. Studies have demonstrated that vanadium oxide coatings improve Lithium-ion battery performance by enhancing electrode stability and charge-discharge efficiency. In supercapacitors, Vanadium Oxide nanoparticles contribute to high energy density and rapid charge storage capabilities, making them essential for next-generation energy storage solutions. Moreover, Vanadium Oxide thin films serve as hole-selective contact layers in solar cells, improving charge extraction efficiency and reducing recombination losses. This leads to enhanced photovoltaic performance and increased device stability by minimizing interface degradation.

 

  1. C. S. Hwang and C. Y. Yoo (eds.), Atomic Layer Deposition for Semiconductors, Springer Science+Business Media New York 2014 https://doi.org/10.1007/978-1-4614-8054-9_1
  2. Klett, U., & Fricke, J. (1998). Gelation of vanadium (V) oxide-triisopropoxide doped silica gels. Journal of non-crystalline solids, 238(1-2), 45-50. https://doi.org/10.1016/S0022-3093(98)00575-4

Kumar, S., Lenoble, D., Maury, F., & Bahlawane, N. (2015). Synthesis of vanadium oxide films with controlled morphologies: Impact on the metal–insulator transition behaviour. physica status solidi (a), 212(7), 1582-1587. https://doi.org/10.1002/pssa.201532325

Safety

Transportation Information
UN1993, Flammable liquids, n.o.s., 3, III (DOT)
Air Transportation Information
UN1993, Flammable liquid, n.o.s., 3, III (IATA)
Pictogram
  • Pictogram: Fire
  • Pictogram: Irritant
Signal Word
Warning
Hazardous Statements
  • H226
    Flammable liquid and vapor.
  • H315
    Causes skin irritation.
  • H319
    Causes serious eye irritation.
  • H335
    May cause respiratory irritation.
Precautionary Phrases
  • P210
    Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
  • P233
    Keep container tightly closed.
  • P240
    Ground/bond container and receiving equipment.
  • P241
    Use explosion-proof electrical/ventilating/lighting/.../equipment.
  • P242
    Use only non-sparking tools.
  • P243
    Take precautionary measures against static discharge.
  • P261
    Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P264
    Wash skin thoroughly after handling.
  • P271
    Use only outdoors or in a well-ventilated area.
  • P280
    Wear protective gloves/protective clothing/eye protection/face protection.
  • P303+P361+P353
    IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
  • P304+P340
    IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
  • P305+P351+P338
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P312
    Call a POISON CENTER or doctor/physician if you feel unwell.
  • P362
    Take off contaminated clothing and wash before reuse.
  • P370+P378
    In case of fire: Use ... for extinction.
  • P403+P233
    Store in a well-ventilated place. Keep container tightly closed.
 
Detailed Safety and Handling Information can be found on our Safety Data Sheet (SDS).