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Barium (II) (2,2,6,6-tetramethyl-3,5-heptanedionato) Hydrate

Properties

Product #
1223
Name
Barium (II) (2,2,6,6-tetramethyl-3,5-heptanedionato) Hydrate
Synonyms
Ba(TMHD)2 hydrate; Barium bis-(2,2,6,6-tetramethyl-3,5-heptanedionato) hydrate; Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)barium hydrate
Formula
Ba(C11H19O2)2.XH2O
Purity
99.9%
CAS Number
17594-47-7
Molecular Weight
503.85 (anhy.)
Color & Form
White Powder
Boiling Point
225° C (dec.)
Melting Point
175-180° C
Solubility in water
Insoluble
$145.00
$600.00
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Information about Barium (II) (2,2,6,6-tetramethyl-3,5-heptanedionato) Hydrate / CAS 17594-47-7

Barium (II) bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato) Hydrate (Ba(TMHD)₂·XH₂O) is a high-purity barium precursor widely used in thin-film synthesis, semiconductor fabrication, catalysis, and advanced material research. As a β-diketonate complex, it offers excellent thermal stability, controlled volatility, and solubility in organic solvents, making it highly effective for metal-organic chemical vapor deposition (MOCVD), atomic layer deposition (ALD), and solution-based processing. These properties have positioned Ba(TMHD)₂·XH₂O as a preferred material in microelectronics, optoelectronics, nanotechnology, renewable energy, and protective coatings.

Ba(TMHD)₂·XH₂O is a versatile precursor in MOCVD and ALD for producing high-purity Barium Oxide (BaO) and barium-containing thin films, vital for applications in ferroelectric capacitors, high-k dielectrics, superconductors, and more. Its precise decomposition ensures uniform film growth, essential for transistors, RF filters, and piezoelectric sensors. It also enhances perovskite-based photovoltaics by improving stability and charge transport for solar cells and flexible electronics. Additionally, Ba(TMHD)₂·XH₂O is used in the synthesis of Barium Titanium Oxide (BaTiO₃) thin films with superior ferroelectric and dielectric properties for capacitors and memory devices. In high-temperature superconductors (HTSCs), it aids in producing YBa₂Cu₃O₇₋ₓ (YBCO) films for quantum computing and MRI technologies. Beyond materials science, Barium (II) bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato) Hydrate is recognized for its efficiency in catalysis and coordination chemistry, facilitating oxidation reactions and organic transformations. Research highlights its role in heterogeneous catalysis for green chemistry, enabling sustainable processes with reduced environmental impact.

As industries advance toward miniaturized electronics, next-generation photovoltaics, and high-efficiency energy storage, Barium (II) bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato) Hydrate remains a critical material for semiconductor fabrication, flexible electronics, and sustainable chemistry. Its proven reliability in MOCVD and ALD, its essential role in high-performance electronics and superconductors, and its expanding applications in catalysis and nanotechnology make it an indispensable choice for researchers and industry professionals.

 

  1. Gardiner, R.A., Kirlin, P.S., Hussein, G.A.M., Gates, B.C. (1992).  Reaction of Barium bis(β-Diketonate) Complexes with the Surface of Magnesium Oxide, MRS Online Proc. Lib. 271, 933
  2. Micard, Q., Pellegrino, A. L., Nigro, R. L., Bartasyte, A., Condorelli, G. G., & Malandrino, G. (2020). Piezoelectric Ba and Ti co-doped BiFeO 3 textured films: selective growth of solid solutions or nanocomposites. Journal of Materials Chemistry C, 8(45), 16168-16179.
  3. Lee, J. H., & Rhee, S. W. (2001). Low temperature chemical vapor deposition of (Ba, Sr) TiO3 thin films with Ti (mpd)(tmhd) 2 as a Ti Source. Journal of The Electrochemical Society, 148(6), C409.

Safety

Transportation Information
UN1564, Barium compounds, n.o.s., 6.1, III (DOT)
Air Transportation Information
UN1564, Barium compound, n.o.s., 6.1, III (IATA)
Pictogram
  • Pictogram: Acute
  • Pictogram: Irritant
Signal Word
Danger
Hazardous Statements
  • H301+H311+H331
    Toxic if swallowed, in contact with skin, or if inhaled.
  • H315
    Causes skin irritation.
  • H319
    Causes serious eye irritation.
  • H335
    May cause respiratory irritation.
Precautionary Phrases
  • P261
    Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P264
    Wash skin thoroughly after handling.
  • P270
    Do not eat, drink or smoke when using this product.
  • P271
    Use only outdoors or in a well-ventilated area.
  • P280
    Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P310
    IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
  • P302+P352
    IF ON SKIN: wash with plenty of soap and water.
  • P304+P340
    IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
  • P305+P351+P338
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P403+P233
    Store in a well-ventilated place. Keep container tightly closed.
 
Detailed Safety and Handling Information can be found on our Safety Data Sheet (SDS).

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