Boron Phosphate
Properties
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Information about Boron Phosphate / CAS 13308-51-5
Boron Phosphate (BPO4) is a white infusible powder. As a source of Boron, it is used as a fertilizer in agriculture. As a source of phosphate, it can be used to prepare metal phosphates by solid-state exchange reactions. It is also used as a catalyst for dehydration reactions in organic synthesis and is being investigated for use in flame retardants.
Boron Phosphate, due to its poor water solubility, is an effective Boron fertilizer, outperforming borax, ulexite, and colemanite in toxicity studies as it is less harmful to seedlings. It also serves as a precursor for solid-state reactions at moderate temperatures, reacting with various metal compounds to form transition metal phosphates.
In organic chemistry, it is used as a catalyst for dehydration reactions, such as the conversion of 1,2-propanediol to propanol, showing superior catalytic activity and durability. Its high-temperature stability also makes it ideal for flame retardants, offering a low-cost, low-toxicity alternative to traditional options.
- Abat, M., Degryse, F., Baird, R., & McLaughlin, M. J. (2015). Boron phosphates (BPO4) as a seedling-safe boron fertilizer source. Plant and Soil, 391(1–2), 153–160. https://doi.org/10.1007/S11104-015-2424-6/METRICS
- Vasovic, D. D., Stojakovic, D. R., & Zec, S. P. (1997). Metal phosphate preparation using boron phosphate. Materials Research Bulletin, 32(6), 779–784. https://doi.org/10.1016/S0025-5408(97)00043-3
- Vasović, D. D., & Stojaković, D. R. (1994). Use of Boron Phosphate in the Solid-State Preparation of Crystalline Iron(III) Phosphate and Manganese(II) Diphosphate. Journal of the American Ceramic Society, 77(5), 1372–1374. https://doi.org/10.1111/J.1151-2916.1994.TB05419.X
- Otomo, R., Yamaguchi, C., Iwaisako, D., Oyamada, S., & Kamiya, Y. (2019). Selective Dehydration of 1,2-Propanediol to Propanal over Boron Phosphate Catalyst in the Presence of Steam. ACS Sustainable Chemistry and Engineering, 7(3), 3027–3033. https://doi.org/10.1021/ACSSUSCHEMENG.8B04594/SUPPL_FILE/SC8B04594_SI_001.PDF
- Hutchings, G. J., Hudson, I. D., & Timms, D. G. (1994). Reactivation of boron phosphate catalysts for the synthesis of isoprene from 2-methylbutanal dehydration. Journal of the Chemical Society, Chemical Communications, 23, 2717–2718. https://doi.org/10.1039/C39940002717
- Shen, K. K. (2019). Recent advances in boron-based flame retardants. Flame Retardant Polymeric Materials: A Handbook, 97–117. https://doi.org/10.1201/B22345-6/RECENT-ADVANCES-BORON-BASED-FLAME-RETARDANTS-KELVIN-SHEN
Safety
- H302 Harmful if swallowed.
- H315 Causes skin irritation.
- H319 Causes serious eye irritation.
- H335 May cause respiratory irritation.
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
- P264 Wash skin thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P281 Use personal protective equipment as required.
- P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
- P302+P352 IF ON SKIN: wash with plenty of soap and water.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P308+P313 IF exposed or concerned: Get medical advice/attention.

