ProChemPolygon-product

Boron Phosphate

Properties

Product #
1296
Name
Boron Phosphate
Synonyms
Borophosphoric acid
Formula
BPO4
CAS Number
13308-51-5
Molecular Weight
105.78
Color & Form
White powder
Melting Point
> 1400° C
Specific Gravity
2.81
Solubility in water
Insoluble
$110.00
$440.00
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Information about Boron Phosphate / CAS 13308-51-5

Boron Phosphate (BPO4) is a white infusible powder.  As a source of Boron, it is used as a fertilizer in agriculture.  As a source of phosphate, it can be used to prepare metal phosphates by solid-state exchange reactions.  It is also used as a catalyst for dehydration reactions in organic synthesis and is being investigated for use in flame retardants.

Boron Phosphate, due to its poor water solubility, is an effective Boron fertilizer, outperforming borax, ulexite, and colemanite in toxicity studies as it is less harmful to seedlings. It also serves as a precursor for solid-state reactions at moderate temperatures, reacting with various metal compounds to form transition metal phosphates.

In organic chemistry, it is used as a catalyst for dehydration reactions, such as the conversion of 1,2-propanediol to propanol, showing superior catalytic activity and durability. Its high-temperature stability also makes it ideal for flame retardants, offering a low-cost, low-toxicity alternative to traditional options.

 

  1. Abat, M., Degryse, F., Baird, R., & McLaughlin, M. J. (2015). Boron phosphates (BPO4) as a seedling-safe boron fertilizer source. Plant and Soil, 391(1–2), 153–160. https://doi.org/10.1007/S11104-015-2424-6/METRICS
  2. Vasovic, D. D., Stojakovic, D. R., & Zec, S. P. (1997). Metal phosphate preparation using boron phosphate. Materials Research Bulletin, 32(6), 779–784. https://doi.org/10.1016/S0025-5408(97)00043-3
  3. Vasović, D. D., & Stojaković, D. R. (1994). Use of Boron Phosphate in the Solid-State Preparation of Crystalline Iron(III) Phosphate and Manganese(II) Diphosphate. Journal of the American Ceramic Society, 77(5), 1372–1374. https://doi.org/10.1111/J.1151-2916.1994.TB05419.X
  4. Otomo, R., Yamaguchi, C., Iwaisako, D., Oyamada, S., & Kamiya, Y. (2019). Selective Dehydration of 1,2-Propanediol to Propanal over Boron Phosphate Catalyst in the Presence of Steam. ACS Sustainable Chemistry and Engineering, 7(3), 3027–3033. https://doi.org/10.1021/ACSSUSCHEMENG.8B04594/SUPPL_FILE/SC8B04594_SI_001.PDF
  5. Hutchings, G. J., Hudson, I. D., & Timms, D. G. (1994). Reactivation of boron phosphate catalysts for the synthesis of isoprene from 2-methylbutanal dehydration. Journal of the Chemical Society, Chemical Communications, 23, 2717–2718. https://doi.org/10.1039/C39940002717
  6. Shen, K. K. (2019). Recent advances in boron-based flame retardants. Flame Retardant Polymeric Materials: A Handbook, 97–117. https://doi.org/10.1201/B22345-6/RECENT-ADVANCES-BORON-BASED-FLAME-RETARDANTS-KELVIN-SHEN

 

Safety

Transportation Information
Not a dangerous good
Pictogram
  • Pictogram: Irritant
Signal Word
Warning
Hazardous Statements
  • H302
    Harmful if swallowed.
  • H315
    Causes skin irritation.
  • H319
    Causes serious eye irritation.
  • H335
    May cause respiratory irritation.
Precautionary Phrases
  • P261
    Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P264
    Wash skin thoroughly after handling.
  • P270
    Do not eat, drink or smoke when using this product.
  • P281
    Use personal protective equipment as required.
  • P301+P312
    IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
  • P302+P352
    IF ON SKIN: wash with plenty of soap and water.
  • P305+P351+P338
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P308+P313
    IF exposed or concerned: Get medical advice/attention.
 
Detailed Safety and Handling Information can be found on our Safety Data Sheet (SDS).